1,1,12,12-TETRA-NORMAL-BUTYL[1.1]STANNAFERROCENOPHANE - PREPARATION AND CRYSTAL AND MOLECULAR-STRUCTURE Academic Article

abstract

• The compound 1,1,12,12-tetra-n-butyl[1.1]stannaferrocenophane, C36H52Fe2Sn2, was obtained from the reaction of 1,1-dilithioferrocene-tetramethylethylenediamine with di-n-butyltin dichloride. The crystal is triclinic with a = 10.217(3), b = 10.748(4), c = 10.173(3) , = 116.34(3), = 90.21(2), = 116.35(2), V = 868.7 3. The structure was solved by conventional three-dimensional Patterson heavy-atom methods using 4013 unique reflections having intensities greater than 3. Refinement was carried out by a full-matrix least-squares technique to a final R of 0.046. The molecule consists of two ferrocene moieties linked to each other through tin atoms. Bond distances and angles are regular. One butyl group on each tin atom is disordered. 1983.

authors

• Clearfield, Abraham

published proceedings

• INORGANICA CHIMICA ACTA-ARTICLES

author list (cited authors)

• CLEARFIELD, A., SIMMONS, C. J., WITHERS, H. P., & SEYFERTH, D.

citation count

• 40

complete list of authors

• CLEARFIELD, A||SIMMONS, CJ||WITHERS, HP||SEYFERTH, D

publication date

• January 1983

publisher

• Elsevier  Publisher

published in

• Inorganica Chimica Acta  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0020-1693(00)91201-5

start page

• 139

end page

• 144

volume

• 75

issue

• 1

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fs0020-1693%2800%2991201-5