Synthesis and structure of copper-DMPLED complex, a bifunctional ligand with positive charged pyridine rings Academic Article

abstract

• N,N-bis(3-hydroxy-1,2-dimethyl-5-hydroxymethyl-4-pyridyl-methyl) ethylenediamine-N,N-diacetic acid, DMPLED and its copper complex has been synthesized and characterized with FAB-MS, elemental analysis and x-ray diffraction. The polyhedra of the Cu complex is described as a Jahn-Teller distorted octahedron with two axes elongated (Cu-O(1), Cu-O(4) are 2.481(4) and 2.676(4) A, respectively). Cu-O(7), Cu-O(8), Cu-N(1) and Cu-N(2) are 1.914(4), 1.929(4), 1.998(6) and 2.019(5) , respectively. 2002 Elsevier Science B.V. All rights reserved.

authors

• Clearfield, Abraham

published proceedings

• INORGANIC CHEMISTRY COMMUNICATIONS

author list (cited authors)

• Kong, D. Y., Mao, J. G., Clearfield, A., & Martell, A. E.

citation count

• 3

complete list of authors

• Kong, DY||Mao, JG||Clearfield, A||Martell, AE

publication date

• August 2002

publisher

• Elsevier  Publisher

published in

• Inorganic Chemistry Communications  Journal

keywords

• Bifunctional
• Complex
• Copper
• Dmpled
• Ligand

Digital Object Identifier (DOI)

• 10.1016/S1387-7003(02)00511-7

start page

• 625

end page

• 628

volume

• 5

issue

• 8

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fs1387-7003%2802%2900511-7