ZIRCONIUM ARSENATES AND THEIR ION EXCHANGE BEHAVIOUR Academic Article

abstract

• When aqueous solutions of Zr(IV) compounds are allowed to react with arsenate ion, amorphous gels of variable composition are obtained. However, a crystalline zirconium monohydrogen arsenate is obtained on refluxing the gels in a strongly acid (HNO3) solution of arsenic acid. The crystalline arsenate is isomorphous with crystalline zirconium monohydrogen phosphate and exhibits quite similar ion exchange behaviour. Some comments on the mechanism of exchange are presented based on structural considerations. 1968.

authors

• Clearfield, Abraham

published proceedings

• JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY

altmetric score

• 3

author list (cited authors)

• CLEARFIELD, A., SMITH, G. D., & HAMMOND, B.

citation count

• 28

complete list of authors

• CLEARFIELD, A||SMITH, GD||HAMMOND, B

publication date

• January 1968

publisher

• Elsevier  Publisher

published in

• Journal of Inorganic and Nuclear Chemistry  Journal

Digital Object Identifier (DOI)

• 10.1016/0022-1902(68)80091-0

start page

• 277

end page

• +

volume

• 30

issue

• 1

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2F0022-1902%2868%2980091-0