MECHANISM OF ION-EXCHANGE IN ZIRCONIUM-PHOSPHATES .15. EFFECT OF CRYSTALLINITY OF EXCHANGER ON LI+-H+ EXCHANGE OF ALPHA-ZIRCONIUM PHOSPHATE Academic Article

abstract

• The effect of the crystallinity of -zirconium phosphate exchangers upon Li+/H+ exchange reactions was investigated. The most crystalline exchanger formed three exchanged phases of approximate composition ZrLi0.9-1.04H1.1-0.96(PO4) 24H2O, ZrLi1.33-1.50H0.67-0.50(PO4) 24H2O, and Zr(LiPO4)24H2O. As the crystallinity of the exchanger decreases the composition ranges of the exchanged phases broaden until with amorphous exchangers only a single solid solution is obtained. The exchange reaction with the amorphous zirconium phosphate is reversible with KLi/H = 6.2 10-5.

authors

• Clearfield, Abraham

published proceedings

• JOURNAL OF PHYSICAL CHEMISTRY

author list (cited authors)

• CLEARFIELD, A., & TUHTAR, D. A.

citation count

• 16

complete list of authors

• CLEARFIELD, A||TUHTAR, DA

publication date

• June 1976

publisher

• American Chemical Society (ACS)  Publisher

published in

• The Journal of physical chemistry  Journal

Digital Object Identifier (DOI)

• 10.1021/j100553a007

start page

• 1296

end page

• 1301

volume

• 80

issue

• 12

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fj100553a007