Nickel Oxide Interstratified agr-Zirconium Phosphate, a Composite Exhibiting Ferromagnetic Behavior.
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As part of an ongoing research program to synthesize novel pillared layered materials, nickel and cobalt hydroxyacetates were inserted between the layers of amine intercalates of alpha-zirconium phosphate. The structure of the resultant nickel composite, derived from x-ray powder data, was found to consist of a three-tiered layer of nickel atoms bridged by hydroxo and acetato groups. Heating to 420 degrees C converted the hydroxyacetate layers to oxide and imparted ordered magnetic domains to the composite. The phosphate layers appear to act as a template directing the growth of the inserted layers in this class of composite materials.
author list (cited authors)
Shpeizer, B., Poojary, D. M., Ahn, K., Runyan, C. E., & Clearfield, A.
complete list of authors
Shpeizer, B||Poojary, DM||Ahn, K||Runyan, CE||Clearfield, A