Novel Chiral “Calixsalen” Macrocycle and Chiral Robson-type Macrocyclic Complexes Academic Article uri icon

abstract

  • A family of novel chiral "calixsalen" Schiff base macrocycles R,R-H(3)L4, R,R-H(3)L5, containing three chiral diamino moieties were synthesized by an efficient self-assembly and characterized by (1)H and (13)C NMR, mass spectrometry, and X-ray diffraction. The systematic synthesis, structure, and coordination properties of the [2 + 2] and [3 + 3] Robson-type Schiff base macrocyclic mono-, di-, tri-, and tetranuclear metal complexes were explored.

altmetric score

  • 1

author list (cited authors)

  • Gao, J., Reibenspies, J. H., Zingaro, R. A., Woolley, F. R., Martell, A. E., & Clearfield, A.

citation count

  • 73

publication date

  • January 2005