Oxo-, hydroxo-, and peroxo-bridged Fe(III) phosphonate cages. Academic Article

abstract

• A series of five Fe(III) phosphonate clusters with four different topologies is reported. The choice of coligand carboxylate plays an important role in directing the structure of the molecule. [Fe9(O)4(O2CCMe3)13(C10P)3] (1) and [Fe9(O)2(OH)(CO2Ph)10(C10P)6(H2O)2](CH3CN)7 (2; camphyl phosphonic acid, C10H17PO3H2 = C10PH2) represent two unprecedented nonanuclear Fe(III) cages having Fe9O4 and Fe9(O)2(OH) core structures, respectively. Whereas [Fe6O2(O)2(O2CCMe3)8(C10P)2 (H2O)2](CH3CN)4 (3) is a peroxo-bridged hexameric compound with an Fe6(O)2(O2) core. [Fe4(O)(O2CCMe3)4(C10P)3(Py)4](CH3CN)3 (4) and [Fe4(O)(O2CPh)4(C10P)3(Py)4](Py)3(CH3CN)2 (5; Py = pyridine) represents two tetranuclear clusters with the same Fe4O core structure.

authors

• Clearfield, Abraham

published proceedings

• J Am Chem Soc

author list (cited authors)

• Konar, S., Bhuvanesh, N., & Clearfield, A.

citation count

• 101

complete list of authors

• Konar, Sanjit||Bhuvanesh, Nattamai||Clearfield, Abraham

publication date

• August 2006

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• 0302 Inorganic Chemistry

PubMed Central ID

• 16866494

Digital Object Identifier (DOI)

• 10.1021/ja063388s

start page

• 9604

end page

• 9605

volume

• 128

issue

• 30

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fja063388s