Mixed-Valent Dodecanuclear Vanadium Cluster Encapsulating Chloride Anions and Its Reaction To Form a “Bowl”-Shaped Cluster
Academic Article
Overview
Research
Identity
Additional Document Info
View All
Overview
abstract
Two oxovanadium phosphonate cage compounds have been synthesized in an organic solvent, and their characterization has been done by single-crystal X-ray analysis, IR spectroscopy, and bond valence sum calculations. The simple reaction of a mixed-valent closed V12 cage system produced another quasi-closed system composed of two V6 bowl-type cages.
