Mixed-valent dodecanuclear vanadium cluster encapsulating chloride anions and its reaction to form a "bowl"-shaped cluster. Academic Article

abstract

• Two oxovanadium phosphonate cage compounds have been synthesized in an organic solvent, and their characterization has been done by single-crystal X-ray analysis, IR spectroscopy, and bond valence sum calculations. The simple reaction of a mixed-valent closed V12 cage system produced another quasi-closed system composed of two V6 bowl-type cages.

authors

• Clearfield, Abraham

published proceedings

• Inorg Chem

author list (cited authors)

• Konar, S., & Clearfield, A.

citation count

• 49

complete list of authors

• Konar, Sanjit||Clearfield, Abraham

publication date

• May 2008

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry: including bioinorganic chemistry  Journal

keywords

• 0306 Physical Chemistry (incl. Structural)

PubMed Central ID

• 18380428

Digital Object Identifier (DOI)

• 10.1021/ic800013f

start page

• 3492

end page

• 3494

volume

• 47

issue

• 9