Solvothermal synthesis and characterization of two high-nuclearity mixed-valent manganese phosphonate clusters. Academic Article

abstract

• Two novel mixed-valent manganese (Mn(II)/Mn(III)) cluster compounds were synthesized in solvothermal reactions and characterized by single-crystal X-ray diffraction, bond valence sum calculations, IR spectra, elemental analysis, and magnetic measurements. Compound 1 is a Mn 19 cluster with a cylindrical core structure. Compound 2 possess a Mn 16 core where all of the manganese sites have unique ligation environments. The magnetic measurements on both compounds indicate dominant antiferromagnetic interactions between the metal centers.

authors

• Clearfield, Abraham

published proceedings

• Inorg Chem

author list (cited authors)

• Konar, S., & Clearfield, A.

citation count

• 63

complete list of authors

• Konar, Sanjit||Clearfield, Abraham

publication date

• May 2008

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• 0306 Physical Chemistry (incl. Structural)

PubMed Central ID

• 18376822

Digital Object Identifier (DOI)

• 10.1021/ic8001493

start page

• 3489

end page

• 3491

volume

• 47

issue

• 9

URL

• http%3A%2F%2Fdx.doi.org%2F10.1021%2Fic8001493