Polymer-bound osmium oxide catalysts Academic Article uri icon

abstract

  • Polymer-supported oxidic osmium catalysts based on cross-linked poly(4-vinyl pyridine) were synthesized by various routes and characterized by a number of physical techniques (Raman, IR, XPS, 13C and 15N solid-state NMR spectroscopy). Model compounds of type Os2O6L4 (L = pyridine, 4-iso-propyl pyridine, and 4-tert-butyl pyridine) were obtained under the conditions of the catalyst synthesis. The catalytic systems were successful in the dihydroxylation of alkenes.

author list (cited authors)

  • Herrmann, W. A., Kratzer, R. M., Bl├╝mel, J., Friedrich, H. B., Fischer, R. W., Apperley, D. C., Mink, J., & Berkesi, O.

citation count

  • 41

publication date

  • June 1997