Photochemical 1,2 Shift of the Phosphane Ligands in the Silanediyl Complex [(2‐Ph2PCH2C6H4)2SiCr(CO)5] Academic Article uri icon


  • An effective access to compounds with three‐coordinate silicon is provided by the title reaction [Eq. (a)], which occurs in two successive steps. Compounds 1 and 3 were completely characterized, but compound 2 could only be detected by IR spectroscopy. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

author list (cited authors)

  • Handwerker, H., Paul, M., Blümel, J., & Zybill, C.

citation count

  • 25

publication date

  • September 1993