PHOTOCHEMICAL 1,2 SHIFT OF THE PHOSPHANE LIGANDS IN THE SILANEDIYL COMPLEX [(2-PH2PCH2C6H4)2SI=CR(CO)5]
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An effective access to compounds with threecoordinate silicon is provided by the title reaction [Eq. (a)], which occurs in two successive steps. Compounds 1 and 3 were completely characterized, but compound 2 could only be detected by IR spectroscopy. (Figure Presented.) Copyright 1993 by VCH Verlagsgesellschaft mbH, Germany