Photochemical 1,2 Shift of the Phosphane Ligands in the Silanediyl Complex [(2‐Ph2PCH2C6H4)2SiCr(CO)5]
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An effective access to compounds with three‐coordinate silicon is provided by the title reaction [Eq. (a)], which occurs in two successive steps. Compounds 1 and 3 were completely characterized, but compound 2 could only be detected by IR spectroscopy. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
author list (cited authors)
Handwerker, H., Paul, M., Blümel, J., & Zybill, C.