Easily immobilized di- and tetraphosphine linkers: rigid scaffolds that prevent interactions of metal complexes with oxide supports. Academic Article

abstract

• Di- and tetraphosphines with rigid phenyl-, biphenyl-, and tetraphenylstannane, -silane, and -methane scaffolds, and various substituents R, have been synthesized and immobilized via triethoxysilane-propagated formation of one or two surface-bound phosphonium moieties. The remaining phosphine groups can be coordinated to metal complexes. All the detective work and proof is done by solid-state NMR spectroscopy.

authors

• Bluemel, Janet

published proceedings

• J Am Chem Soc

author list (cited authors)

• Yang, Y., Beele, B., & Blmel, J.

citation count

• 46

complete list of authors

• Yang, Yuan||Beele, Björn||Blümel, Janet

publication date

• March 2008

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• Binding Sites
• Magnetic Resonance Spectroscopy
• Organometallic Compounds
• Oxides
• Phosphines
• Reference Standards
• Silicon
• Surface Properties
• TiN

PubMed Central ID

• 18311988

Digital Object Identifier (DOI)

• 10.1021/ja800541c

start page

• 3771

end page

• 3773

volume

• 130

issue

• 12