New mechanistic insights regarding Pd/Cu catalysts for the Sonogashira reaction: HRMAS NMR studies of silica-immobilized systems. Academic Article uri icon


  • The title technique, high-resolution magic angle spinning NMR of suspensions, constitutes a powerful new tool for investigating the structures and mobilities of immobilized species and, thus, for optimizing heterobimetallic catalyst systems, such as the Sonogashira coupling of terminal alkynes and aryl halides.

published proceedings

  • J Am Chem Soc

author list (cited authors)

  • Posset, T., & Blmel, J.

citation count

  • 64

complete list of authors

  • Posset, Tobias||Bl├╝mel, Janet

publication date

  • July 2006