New mechanistic insights regarding Pd/Cu catalysts for the Sonogashira reaction: HRMAS NMR studies of silica-immobilized systems. Academic Article

abstract

• The title technique, high-resolution magic angle spinning NMR of suspensions, constitutes a powerful new tool for investigating the structures and mobilities of immobilized species and, thus, for optimizing heterobimetallic catalyst systems, such as the Sonogashira coupling of terminal alkynes and aryl halides.

authors

• Bluemel, Janet

published proceedings

• J Am Chem Soc

author list (cited authors)

• Posset, T., & Blmel, J.

citation count

• 64

complete list of authors

• Posset, Tobias||Blümel, Janet

publication date

• July 2006

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• Alkynes
• Catalysis
• Copper
• Magnetic Resonance Spectroscopy
• Molecular Structure
• Organometallic Compounds
• Palladium
• Sensitivity And Specificity
• Silicon Dioxide

PubMed Central ID

• 16802793

Digital Object Identifier (DOI)

• 10.1021/ja062206r

start page

• 8394

end page

• 8395

volume

• 128

issue

• 26