Synthesis, structure, immobilization and solid-state NMR of new dppp- and tripod-type chelate linkers Academic Article

abstract

• Chelating phosphines incorporating ethoxysilane functions for immobilizations have been synthesized and fully characterized. (EtO)Si(CH 2PPh2)3, (EtO)2Si(CH 2PPh2)2, and Si(CH2PPh 2)4 could be prepared in high yields from cheap starting materials. The ethoxysilanes, as well as a Pd complex thereof have been characterized by X-ray structures, and immobilized on silica. The success of the immobilization was proved by 31P solid-state NMR of the dry materials and of the suspensions. Two representative chelate metal complexes, (EtO)2Si(CH2PPh2)2PdCl2 and (EtO)Si(CH2PPh2)3W(CO)3 have been synthesized, characterized and immobilized. 2005 Elsevier B.V. All rights reserved.

authors

• Bluemel, Janet

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• Bogza, M., Oeser, T., & Blumel, J.

citation count

• 27

complete list of authors

• Bogza, M||Oeser, T||Blumel, J

publication date

• January 2005

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• Chelating Phosphines
• Ethoxysilanes
• Immobilization
• Linkers
• Pd Catalyst
• Solid-state NMR

Digital Object Identifier (DOI)

• 10.1016/j.jorganchem.2005.04.021

start page

• 3383

end page

• 3389

volume

• 690

issue

• 14

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fj.jorganchem.2005.04.021