Stepwise Stacking of Three Paramagnetic Metallocene Units: [CpNiCp(SiMe2)2CpCrCp(SiMe2)2CpNiCp]
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For molecular magnetic materials, 1 is the prototype of a stepped stack in which the different paramagnetic building blocks are cova‐lently linked. Such a structure leads to antiferromagnetism. 1 can be considered to be a fragment of a polymer, but the experimental advantages of uniform composition and solubility that it offers allow examination by cyclovoltammetry and NMR spectroscopy. (Figure Presented.) Copyright © 1992 by VCH Verlagsgesellschaft mbH, Germany
author list (cited authors)
Bergerat, P., Blümel, J., Fritz, M., Hiermeier, J., Hudeczek, P., Kahn, O., & Köhler, F. H.