STEPWISE STACKING OF 3 PARAMAGNETIC METALLOCENE UNITS - [CPNICP(SIME2)2CPCRCP(SIME2)2CPNICP]
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For molecular magnetic materials, 1 is the prototype of a stepped stack in which the different paramagnetic building blocks are covalently linked. Such a structure leads to antiferromagnetism. 1 can be considered to be a fragment of a polymer, but the experimental advantages of uniform composition and solubility that it offers allow examination by cyclovoltammetry and NMR spectroscopy. (Figure Presented.) Copyright 1992 by VCH Verlagsgesellschaft mbH, Germany