Immobilization and chelation of metal complexes with bifunctional phosphine ligands: A solid-state NMR study
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abstract
29Si CP MAS NMR shows that a transition-metal complex with two bifunctional phosphine ligands such as (CO)2Ni[PPh2(C6H4)SiMe 2OEt]2, when attached to a silica surface according to a commonly used procedure, is mainly anchored by just one ligand.