BLOCKING OF THE RETRO-DIELS-ALDER REACTION BY COMPLEX-FORMATION - [(ETA-5-CYCLOPENTADIENYL)(ETA-5-DICYCLOPENTADIENYL)IRON] Academic Article

abstract

• In the case of lithium compound 1 the retroDielsAlder reaction does not have to be accelerated artificiallyquite the opposite! 1 represents a rare case in that it reacts before it can be investigated. It has now been possible to trap 1 as the title compound 2 with solvated iron(II) chloride. 2 is also of interest with regard to its possible chemical reactions. It is reminiscent of ferrocene, but has a highly distorted system. (Figure Presented.) Copyright 1988 by VCH Verlagsgesellschaft mbH, Germany

authors

• Bluemel, Janet

published proceedings

• ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH

author list (cited authors)

• BLUMEL, J., KOHLER, F. H., MULLER, G., & WILKINSON, D. L.

citation count

• 8

complete list of authors

• BLUMEL, J||KOHLER, FH||MULLER, G||WILKINSON, DL

publication date

• January 1988

publisher

• Wiley  Publisher

published in

• Angewandte Chemie - International Edition  Journal

keywords

• Biodefense
• Prevention
• Vaccine Related

Digital Object Identifier (DOI)

• 10.1002/anie.198809771

start page

• 977

end page

• 979

volume

• 27

issue

• 7

URL

• http%3A%2F%2Fdx.doi.org%2F10.1002%2Fanie.198809771