Improved rhodium hydrogenation catalysts immobilized on oxidic supports
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abstract
Wilkinson-type rhodium hydrogenation catalysts immobilized on oxidic supports via mono-and bidentate phosphine linkers have been studied by 31P solid-state NMR, and their recycling stability and lifetime with respect to hydrogenation of 1-dodecene, 2-cyclohexen-1-one, and 4-bromostyrene have been improved substantially.