New bifunctional chelating phosphine ligands for immobilization of metal complexes on oxidic supports Academic Article

abstract

• The immobilization of transition metal complexes by bifunctional phosphines containing ethoxysilane groups is of widespread interest. Especially desirable are chelating phosphines, since they can reduce leaching of the metal complexes. Easy syntheses of the bifunctional chelating ethoxysilane phosphines Ph 2 PCH 2 CH[OSi(OEt) 3 ]CH 2 PPh 2 , and Ph 2 P(CH 2 ) x PPh(CH 2 ) y Si(OEt) 3 (x = 2, 3; y = 2, 3), and the nickel derivative (CO) 2 Ni[Ph 2 P(CH 2 ) 2 PPh (CH 2 ) 2 Si(OEt) 3 ] are reported. The ethoxysilane groups present convenient handles for immobilization on oxidic supports.

authors

• Bluemel, Janet

published proceedings

• SYNLETT

author list (cited authors)

• Tsiavaliaris, G., Haubrich, S., Merckle, C., & Blumel, J.

complete list of authors

• Tsiavaliaris, G||Haubrich, S||Merckle, C||Blumel, J

publication date

• March 2001

published in

• Synlett: accounts and rapid communications in synthetic organic chemistry  Journal

keywords

• Bifunctional Ligands
• Chelating Ligands
• Immobilized Catalysts
• Silica Support
• Solid-state NMR

start page

• 391

end page

• 393

issue

• 3