DIPHENYLPHOSPHINATED ETHYLENE OLIGOMERS AS POLYMERIC REAGENTS FOR SYNTHESIS OF ALKYL CHLORIDES FROM ALCOHOLS
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Diphenylphosphinated ethylene oligomers can be used as homogeneous polymeric reagents at 90 C in carbon tetrachloride to form alkyl chlorides from alcohols and since these functionatized ethylene oligomers precipitate quantitatively from solution at 25 C, they can be easily recovered and separated from the reaction products and can be partially recycled.