Heck reactions: a caveat on the use of palladium(II) PCP-type catalysts Academic Article

abstract

• A PCP-type catalyst was prepared and examined within the context of intramolecular Heck reactions. A substrate possessing a 1,4-diene system effectively poisoned the PCP catalyst leading to no reaction. This behavior contrasts with the typical palladium(0) catalyst system.

authors

• Bergbreiter, David

published proceedings

• TETRAHEDRON LETTERS

author list (cited authors)

• Kiewel, K., Liu, Y. S., Bergbreiter, D. E., & Sulikowski, G. A.

citation count

• 49

complete list of authors

• Kiewel, K||Liu, YS||Bergbreiter, DE||Sulikowski, GA

publication date

• December 1999

publisher

• Elsevier  Publisher

published in

• Tetrahedron Letters: the international journal for the rapid publication of all preliminary communications in organic chemistry  Journal

keywords

• Heck Reaction
• Pcp-type Catalyst

Digital Object Identifier (DOI)

• 10.1016/S0040-4039(99)01938-3

start page

• 8945

end page

• 8948

volume

• 40

issue

• 51

URL

• http%3A%2F%2Fdx.doi.org%2F10.1016%2Fs0040-4039%2899%2901938-3