Heck reactions: a caveat on the use of palladium(II) PCP-type catalysts Academic Article uri icon

abstract

  • A PCP-type catalyst was prepared and examined within the context of intramolecular Heck reactions. A substrate possessing a 1,4-diene system effectively poisoned the PCP catalyst leading to no reaction. This behavior contrasts with the typical palladium(0) catalyst system.

published proceedings

  • TETRAHEDRON LETTERS

author list (cited authors)

  • Kiewel, K., Liu, Y. S., Bergbreiter, D. E., & Sulikowski, G. A.

citation count

  • 50

complete list of authors

  • Kiewel, K||Liu, YS||Bergbreiter, DE||Sulikowski, GA

publication date

  • December 1999