Large-scale self-assembled zirconium phosphate smectic layers via a simple spray-coating process. Academic Article uri icon


  • The large-scale assembly of asymmetric colloidal particles is used in creating high-performance fibres. A similar concept is extended to the manufacturing of thin films of self-assembled two-dimensional crystal-type materials with enhanced and tunable properties. Here we present a spray-coating method to manufacture thin, flexible and transparent epoxy films containing zirconium phosphate nanoplatelets self-assembled into a lamellar arrangement aligned parallel to the substrate. The self-assembled mesophase of zirconium phosphate nanoplatelets is stabilized by epoxy pre-polymer and exhibits rheology favourable towards large-scale manufacturing. The thermally cured film forms a mechanically robust coating and shows excellent gas barrier properties at both low- and high humidity levels as a result of the highly aligned and overlapping arrangement of nanoplatelets. This work shows that the large-scale ordering of high aspect ratio nanoplatelets is easier to achieve than previously thought and may have implications in the technological applications for similar materials.

published proceedings

  • Nat Commun

altmetric score

  • 34.25

author list (cited authors)

  • Wong, M., Ishige, R., White, K. L., Li, P., Kim, D., Krishnamoorti, R., ... Sue, H.

citation count

  • 89

complete list of authors

  • Wong, Minhao||Ishige, Ryohei||White, Kevin L||Li, Peng||Kim, Daehak||Krishnamoorti, Ramanan||Gunther, Robert||Higuchi, Takeshi||Jinnai, Hiroshi||Takahara, Atsushi||Nishimura, Riichi||Sue, Hung-Jue

publication date

  • January 2014